Le acque del Carso classico : Progetto Hydrokarst

Dopo quasi 200 anni dalle prime ricerche sul Timavo, prende il via il Progetto HYDROKARST nato dalle idee di ricercatori italiani e sloveni che da anni studiano insieme l\u2019idrogeologia carsica (www.hydrokarstproject.eu). Il progetto ha come obiettivo la gestione coordinata e la tutela dell\u2019acquifero transfrontaliero del Reka-Timavo attraverso l\u2019istituzionalizzazione di una rete di monitoraggio quantitativo e qualitativo delle acque ipogee e del territorio del Carso Classico. Il progetto si propone di garantire, attraverso delle partnership stabili, una gestione sostenibile della risorsa acqua rafforzando quella coesione territoriale transfrontaliera che deve portare alla redazione di protocolli congiunti per permettere di uniformare le metodologie di raccolta dati e la loro rappresentazione e codifica, primo passo per la definizione delle aree di salvaguardia delle sorgenti e dei pozzi captati a scopo idropotabile. Va ricordato che ad oggi, le acque del Reka-Timavo non sono legalmente tutelate, cosa che invece accade per quelle del fiume Isonzo-So\u10da. Il progetto \ue8 suddiviso in sette diversi Workpakages (WP). WP1: Progettazione e costruzione del quadro logico per la gestione del progetto. Monitoraggio coordinamento e rendicontazioni. WP2: Ideazione, preparazione e definizione dell\u2019idea progettuale. WP3: Raccolta ed elaborazione dei dati idrodinamici, idrochimici e biologici dell\u2019acquifero del Reka-Timavo. WP4: Vulnerabilit\ue0 degli acquiferi carsici e protocolli di individuazione delle aree di salvaguardia. Uso del suolo. Analisi della stabilit\ue0 della rete di distribuzione e delle necessit\ue0 di approvvigionamento idrico. WP5: Elaborazione della cartografia unificata del Carso Classico. WP6: Elaborazione di protocolli per la gestione condivisa delle risorse e delle riserve acquifere del Carso Classico. WP7: Piano di comunicazione. La fase di condivisione dati ha portato alla realizzazione di una base cartografica unificata e di una banca dati georeferenziata (GIS) di tutto il bacino del Carso Classico. Attraverso la raccolta dati prima, e l\u2019elaborazione poi, si \ue8 giunti alla definizione di un modello concettuale dell\u2019intero acquifero del Reka-Timavo. Buona parte di questi dati hanno successivamente permesso l\u2019elaborazione delle carte di vulnerabilit\ue0, a loro volta determinanti per la delimitazione delle aree di salvaguardia. Il monitoraggio della rete acquedottistica di distribuzione e la realizzazione di interventi per il risparmio idrico hanno permesso di promuovere progetti di minimizzazione delle perdite, ottimizzando tratti poco efficienti delle reti. Scopo ultimo del progetto era pertanto l\u2019elaborazione: \u2013 di accordi di cooperazione e di azioni per la promozione ed attuazione di sistemi per la riduzione delle emissioni inquinanti con particolare riferimento all\u2019acqua potabile; \u2013 di sistemi di intervento congiunti nelle situazioni di emergenza; \u2013 di strategie congiunte per prevenire e ridurre i rischi; \u2013 di interventi per il risparmio idrico, l\u2019efficienza nella gestione della rete idrica ed il miglioramento della qualit\ue0 dell\u2019acqua potabile. Skoraj dvesto let po prvih raziskavah reke Timave so italijanski in slovenski raziskovalci, ki \u17ee ve\u10d let skupaj preu\u10dujejo kra\u161ko hidrogeologijo, oblikovali Projekt HYDROKARST (www.hydrokarst-project.eu). Cilj projekta je koordinirano upravljanje in za\u161\u10dita \u10dezmejnega vodonosnika Reka-Timava z institucionalizacijo omre\u17eja za koli\u10dinsko in kakovostno spremljanje podzemnih voda na obmo\u10dju klasi\u10dnega Krasa. Namen projekta je, da se z vzpostavitvijo stalnega partnerstva zagotovi trajnostno upravljanje vodnega vira, \u10dezmejna teritorialna kohezija in priprava skupnih strokovnih podlag, ki bodo omogo\u10dale poenotenje metodologij zbiranja, prikazovanja in kodifikacije podatkov, kar je prvi korak v smeri definicije za\u161\u10ditenih obmo\u10dij izvirov in zajemali\u161\u10d pitne vode. Naj spomnimo, da vse do dana\u161njih dni vodonosnik Reka-Timava ni bil dele\u17een nikakr\u161ne pravne za\u161\u10dite \u2013 v nasprotju na primer s So\u10do (Isonzo). Projekt sestavlja sedem razli\u10dnih delovnih sklopov (WP): WP1: Oblikovanje \u201cstoritvenega sistema\u201d in priprava logi\u10dnega okvira za upravljanje projekta. Spremljanje projekta, koordiniranje in finan\u10dno poro\u10danje. WP2: Oblikovanje, priprava in dolo\u10ditev projektne ideje. WP3: Meritve in obdelava hidrodinami\u10dnih podatkov vodonosnika Reka-Timava. WP4: Ranljivost kra\u161kih vodonosnikov in protokoli za dolo\u10ditev vodovarstvenih obmo\u10dij. Raba tal. Analiza stabilnosti distribucijskegaomre\u17eja in potreb po vodni preskrbi. WP5: Priprava skupnih kartografskih prikazov mati\u10dnega Krasa. WP6: Priprava protokolov za skupno upravljanje virov in zalog mati\u10dnega Krasa. WP7: Komunikacijska kampanja o razvoju projekta in dose\u17eenih ciljih. Faza izmenjave podatkov je omogo\u10dila vzpostavitev enotnih kartografskih podlag in enotne georeferencirane podatkovne baze (GIS) za celotno obmo\u10dje mati\u10dnega Krasa. Z zbiranjem in obdelavo podatkov smo izdelali konceptualni model celotnega vodonosnika Reka-Timava. Ti podatki so nadalje omogo\u10dili izdelavo kart ranljivosti, ki so bistvenega pomena za dolo\u10ditev vodovarstvenih obmo\u10dij. Spremljanje distribucijskega vodovodnega omre\u17eja in izvajanje ukrepov za var\u10devanje z vodo je omogo\u10dilo implementacijo projektov za zmanj\u161anje izgub z izbolj\u161avami na neu\u10dinkovitih delih omre\u17eja. Kon\u10dni cilj projekta je torej: \u2013 sklenitev protokolov o sodelovanju in dolo\u10ditev ukrepov promocije in uresni\u10denja sistemov za zmanj\u161anje onesna\u17eevalnih emisij, predvsem tistih, ki se nana\u161ajo na pitno vodo; \u2013 razvoj sistemov skupnega poseganja v nujnih primerih; \u2013 oblikovanje skupnih strategij za prepre\u10devanje in zmanj\u161evanje tveganj; \u2013 promocija posegov za var\u10devanje z vodo, u\u10dinkovito upravljanje vodovodnega omre\u17eja in izbolj\u161anje kakovosti pitne vode

Application of different drying techniques to fresh-cut salad waste to obtain food ingredients rich in antioxidants and with high solvent loading capacity

Wastes from iceberg salad fresh-cut processing were submitted to air-drying, freeze-drying, and supercritical-CO2-drying with or without ethanol as co-solvent. Drying was combined with grinding to obtain flours. Samples were analysed for macro- and micro-appearance, particle size, dietary fibre, polyphenol content, antioxidant activity, water vapour sorption, water and oil holding capacity. Air-drying produced a collapsed brown material allowing a flour rich in fibre (>260 g/kg) and polyphenols (3.05 mg GAE/gdw) with antioxidant activity (6.04 OD 123/min/gdw) to be obtained. Freeze-drying maintained vegetable structure and colour while partly retaining polyphenols (1.23 mg GAE/gdw). Supercritical-CO2-drying with ethanol as co-solvent, produced an expanded material able to entrap huge amounts of water and oil (43.2 and 35.2 g of water and oil for g of dry sample). Air-dried salad waste derivatives could be used as functional food ingredients, while supercritical-CO2-dried ones can be exploited as bulking agents and absorbers of oil spills or edible oils. \ua9 2017 Elsevier Lt

Classical Karst hydrodynamics: a shared aquifer within Italy and Slovenia

Abstract. The classical Karst transboundary aquifer is a limestone plateau of 750 km2 that extends from Brkini hills in Slovenia to Isonzo River in Italy. For 20 years, and especially in the last two years, the Mathematic and Geosciences Department of Trieste University has run a monitoring project in order to better understand the groundwater hydrodynamics and the relation between the fracture and conduit systems. A total of 14 water points, including caves, springs and piezometers are monitored and temperature, water level and EC data are recorded. Two sectors are highlighted: the southeastern sector mainly influenced by the sinking of the Reka River, and a northwestern sector connected to the influent character of the Isonzo River. Water table fluctuations are significant, with risings of > 100 m. During floods most of the circuits are under pressure, and only a comparative analysis of water levels, temperature and EC permits a precise evaluation of the water transit times in fractured and/or karstified volumes

Exploring the potentialities of photoinduced glycation to steer protein functionalities: The study case of freeze-dried egg white proteins/carbohydrates mixtures

The capacity of UV-C light to induce glycation and modify functional properties of systems containing freeze-dried egg white proteins and carbohydrates with increasing molecular weight (i.e., glucose, maltose, trehalose and maltodextrin) was studied. Color changes induced by light exposure were taken as typical indicators of glycation. Samples were then analyzed for selected physical (critical concentration, particle size and viscosity), chemical (ovalbumin content) and technofunctional properties (gelling temperature and foaming capacity). The presence of sugars during exposure to UV-C light promoted intense browning and decreased ovalbumin content by circa 30%. Concomitantly, up to a 3-fold increase in critical concentration of the aqueous suspensions of the irradiated protein-carbohydrate powders and changes in particle size were detected. These modifications were consistent with the development of non-enzymatic browning reactions upon UV-C light irradiation. Photoinduced glycation was associated to a decrease in viscosity, a tendency to form gel at temperature lower by up to 8\u25e6C and a better capacity of foam stabilization. The intensity of these changes seems to be affected by the nature of the carbohydrates reacting with proteins, with longer carbohydrates able to produce systems with higher foam stability capacity

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Understanding the impact of moderate-intensity pulsed electric fields (MIPEF) on structural and functional characteristics of pea, rice and gluten concentrates

Aim: The effect of moderate-intensity pulsed electric fields (MIPEF) was evaluated on vegetable protein concentrates from pea, rice, and gluten. Methods: Five percent (w/w) suspensions of protein concentrates (pH 5 and 6) were exposed to up to 60,000 MIPEF pulses at 1.65\ua0kV/cm. Both structural modifications (absorbance at 280\ua0nm, free sulfhydryl groups, FT-IR-spectra) and functional properties (solubility, water and oil holding capacity, foamability) were analyzed. Results: MIPEF was able to modify protein structure by inducing unfolding, intramolecular rearrangement, and formation of aggregates. However, these effects were strongly dependent on protein nature and pH. In the case of rice and pea samples, structural changes were associated with negligible modifications in functional properties. By contrast, noticeable changes in these properties were observed for gluten samples, especially after exposure to 20,000 pulses. In particular, at pH 6, an increase in water and oil holding capacity of gluten was detected, while at pH 5, its solubility almost doubled. Conclusion: These results suggest the potential of MIPEF to steer structure of proteins and enhance their technological functionality

Rheological investigation and simulation of a debris-flow event in the Fella watershed

Abstract. To set an approach for the future territorial planning, the Geological Survey of Friuli Venezia Giulia Region, through the researchers of Trieste University, started a program of debris-flow risk analysis using Flo-2D software as tool to delimit the hazardous areas. In the present paper, as a case study, a debris flow, called Fella sx, occurring in a torrent catchment was analyzed. The choice was due to the abundance of information about past events, inundated areas, rain fall, geology and to its representativeness. An initial back-analysis investigation identified a couple of representative rheological parameters. Riverbed samples were collected, sieve analyses were performed and rheological tests were carried out on the fraction finer than 0.063 mm using a rotationally controlled stress rehometer equipped with the serrated parallel plate geometry. The shear dependent behaviour was examined at different concentrations ranging from 33 to 48%, by weight. Viscosity data treatment was performed to determine the most suitable rheological model to provide the best approximation of the debris-flow behaviour. The rheological parameters, derived from experimental data, were used and compared with those obtained through the back-analysis and with the real inundated area. Data obtained through rheological analysis are useful in constructing scenarios of future events where no data for back-analysis are available

Modeling the effect of the oxidation status of the ingredient oil on stability and shelf life of low-moisture bakery products: The case study of crackers

In packed low-moisture foods such as crackers, oxidation is generally the main cause of quality depletion during storage. It is commonly believed, but scarcely investigated, that product shelf life depends on the oxidative status of the lipid ingredients. In this study, the influence of oxidation degree of the ingredient sunflower oil on cracker oxidative stability and hence shelf life was investigated. To this aim, oil with increasing peroxide values (PVs) (5, 11, and 25 mEqO2/kgoil) was used to prepare crackers. Just after production, crackers presented similar peroxide and rancid odor intensity, probably due to the interactive pathways of oxidative and Maillard reactions. Crackers were packed and analyzed for PV and rancid odor during storage at 20, 40, and 60 \u25e6C. Rancid odor well discriminated cracker oxidative status. Relevant oxidation rates were used to develop a shelf life predictive model based on the peroxide value of the ingredient oil. It was estimated that an oil PV from 5 to 15 mEqO2/kgoil shortens cracker Shelf Life (SL) by 50%, independently of storage temperature. These results demonstrate the critical impact of ingredient quality on product performance on the market

The FOOT GROUND REACTION ON THE SOCCER AND RUGBY PLAYER

Introduction The body’s motion must be interpreted a succession of elementary movements that can be studied as the combination of translational and rotational motions. The correct expression of a motion is dependent on the balance between internal and external forces. The vector and scalar characteristics of the reaction are related to the physical and mechanical characteristics of two structures coming in contact Methods and Materials The analysis is performed during the normal strike and the running of the soccer and the rugby player. We have used a dynamometric platform Kistler that provided the complete progression of the foot ground reaction which deve1opes during the stage of placing of the fool on the ground.24 soccer p layers of Italian national team and 40 soccer players with high ability and performance and 50 rugby players are examined and the tests are correlated with a control reference group of normal subjects. Results The analysis of the soccer players’ foot-ground reaction on the sagittal plane has revealed: during the normal strike an impact phase characterized by high force both maximum and medium and high velocity of progression of application's point. A support phase characterized by velocity of progression of application point lower compared to the impact phase and by the backward inclination of vectors. A propulsive phase with a presence of a peak of force lower than the first one in the contact phase and with rotational moment significantly increased compared to the normal. The trace diagram show a wider extension of internal rotation during the contact phase and movement with a predominance of an external rotation during the support phase. The analysis of the rugby players' fool-ground reaction has revealed on the sagittal plane: during the normal strike an impact phase with high force both maximum and medium and high velocity of progression of application's point. In comparison of the soccer player’s ground reaction the data show values reduced of force during the impact phase. A support phase shows backward inclination of vectors and a reduced velocity of progression compared to the impact phase. A propulsive phase demonstrate a presence of a peak of force same that the first one during the contact phase. On the horizontal plane, the trace diagram shows a normal extension of internal rotation and a significantly extension of external rotation. Conclusions: The ground reaction pattern of the professional soccer player is repetitive, typical and different by the pattern of the vectorial diagram of the rugby player

Steering protein and lipid digestibility by oleogelation with protein aerogels

The aim of the present work was to assess the effect of an innovative oleogelation strategy, the aerogel-template approach, on protein and lipid digestibility. Whey protein isolate (WP) was converted into aerogel particles via supercritical CO2 drying. Oleogels were then prepared by absorption of sunflower (SO) or flaxseed (FLX) oil (80%, w/w) into the aerogel particle template and subjected to in vitro digestion. WP aerogel-templated oleogels showed a specific destructuring behaviour during digestion. Confocal micrographs clearly demonstrated that the original oleogel structure was lost at the gastric level, with the release of oil droplets smaller (D-32 30 mu m), stabilised by undigested aerogel proteins. Sodium dodecyl sulphate polyacrylamide gel electrophoresis (SDS-PAGE) and bicinchoninic acid (BCA) assay confirmed that aerogelation reduced the gastric proteolysis of WP from nearly 100% to 70%. The digestion of the SO oleogel led to similar gastric protein digestibility. In contrast, in the case of the FLX oleogel, gastric proteolysis decreased to 40%, suggesting a role of the oil nature in steering WP aerogel digestion. In all cases, upon intestinal digestion aerogel proteins resulted completely hydrolysed. The lipolysis degree of SO (75%) and FLX (34%) oil in the oleogels was higher than that of the unstructured SO (66%) and FLX (24%) oils, due to the larger surface offered by smaller oil droplets to the action of intestinal lipases. This was confirmed by dynamic light scattering, showing a shift towards smaller size in the digestive micelle distribution of oleogels at the end of the intestinal phase. Oleogelation through the WP aerogel-template approach could be regarded as a strategy to steer lipid digestibility while also modulating the release of bioaccessible peptides